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タイトル
和文:Rhodium-Catalyzed Asymmetric Formal Olefination or Cycloaddition: 1,3-Dicarbonyl Compounds Reacting with 1,6-Diynes or 1,6-Enynes. 
英文:Rhodium-Catalyzed Asymmetric Formal Olefination or Cycloaddition: 1,3-Dicarbonyl Compounds Reacting with 1,6-Diynes or 1,6-Enynes. 
著者
和文: Takeshi Suda, Keiichi Noguchi, Ken. Tanaka.  
英文: Takeshi Suda, Keiichi Noguchi, Ken. Tanaka.  
言語 English 
掲載誌/書名
和文:Angewandte Chemie, International Edition 
英文:Angewandte Chemie, International Edition 
巻, 号, ページ Vol. 50    No. 19    pp. 4475-4479, S4475/1-S4475/59
出版年月 2011年 
出版者
和文:Wiley-VCH Verlag GmbH & Co. KGaA 
英文:Wiley-VCH Verlag GmbH & Co. KGaA 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1002/anie.201007727
アブストラクト The Rh(I)/(R)-H8-BINAP complex was used as the catalyst in the asym. intermol. olefination of enolizable 1,3-dicarbonyl compds. with 1,6-diynes by [2+2+2]cycloaddn. followed by electrocyclic ring opening. The same reaction was also accomplished with 1,6-enynes by using Rh(I)/S-segphos as catalyst. [on SciFinder(R)]

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