A New Route to Substituted Phenols by Cationic Rhodium(I)/BINAP Complex-Catalyzed Decarboxylative [2 + 2 + 2] Cycloaddition.

Hiromi Hara; Masao Hirano; Ken. Tanaka

doi:10.1021/ol900123d

論文・著書情報

タイトル

和文:	A New Route to Substituted Phenols by Cationic Rhodium(I)/BINAP Complex-Catalyzed Decarboxylative [2 + 2 + 2] Cycloaddition.
英文:	A New Route to Substituted Phenols by Cationic Rhodium(I)/BINAP Complex-Catalyzed Decarboxylative [2 + 2 + 2] Cycloaddition.

著者

和文:	Hiromi Hara, Masao Hirano, Ken. Tanaka.
英文:	Hiromi Hara, Masao Hirano, Ken. Tanaka.

言語

English

掲載誌/書名

和文:	Organic Letters
英文:	Organic Letters

巻, 号, ページ

Vol. 11 No. 6 pp. 1337-1340

出版年月

2009年

出版者

和文:	American Chemical Society
英文:	American Chemical Society

会議名称

和文:
英文:

開催地

和文:
英文:

DOI

https://doi.org/10.1021/ol900123d

アブストラクト

A new route to substituted phenols has been developed by cationic rhodium(I)/BINAP complex-catalyzed decarboxylative [2 + 2 + 2] cycloaddns. of 1,6- and 1,7-diynes with com. available vinylene carbonate. Various phenols, indanols, e.g., I (R = Ac, CO2Et), (tetrahydro)naphthalenols, isobenzofuranols, and isoindoles have been prepd. by this method. [on SciFinder(R)]

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