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英文:Preparation of (La1-xSrx)MnO3 (- delta) thin films on Si (100) substrates by a metal-organic decomposition method for smart radiation devices 
著者
和文: 塩田 忠, 森 祐子, 杉山 醇, 櫻井 修, 西山 昭雄, 脇谷 尚樹, 太刀川 純孝, 篠崎 和夫.  
英文: Tadashi Shiota, Yuko Mori, Jun Sugiyama, Osamu Sakurai, Akio Nishiyama, Naoki Wakiya, Sumitaka Tachikawa, Kazuo Shinozaki.  
言語 English 
掲載誌/書名
和文: 
英文:Thin Solid Films 
巻, 号, ページ Vol. 626        pp. 154-158
出版年月 2017年3月31日 
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会議名称
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DOI https://doi.org/10.1016/j.tsf.2017.02.037
アブストラクト (La1-xSrx)MnO3-(delta) (LSMO) thin films were prepared on Si(100) substrates using a metal-organic decomposition (MOD) technique for smart radiation devices used for thermal control in spacecraft. The 6 wt% concentration MOD precursor solutions were spin-coated on Si substrates. The coated films were dried at 90 degrees C and pyrolytically decomposed at 530 degrees C. Finally, they were annealed in air at 750 degrees C to obtain dense, polycrystalline, and singlephase perovskite LSMO films. A ferromagnetic-paramagnetic phase transition was observed close to room temperature in a LSMO film. The thermal emittance of the film was changed as a result of this phase transition. The phase transition temperature increased with an increasing Sr ratio at the A-site of the LSMO and decreased after annealing under a reduced atmosphere. Based on this result, we propose that the temperature range where the thermal emittance is widely variable can be finely tuned on demand with post-annealing.

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