Reduction of a diruthenium bridging vinylidene species Cp(2)RU(2)(mu-C=CH2)(CO)(mu-CO)(MeCN) by hydrosilane leading to a vinyl complex Cp(2)Ru(2)(mu-CH=CH2)(CO)(2)(SiR(3)) and vinylsilane: A model system for production of an olefinic product from a vinylidene intermediate
英文:
Reduction of a diruthenium bridging vinylidene species Cp(2)RU(2)(mu-C=CH2)(CO)(mu-CO)(MeCN) by hydrosilane leading to a vinyl complex Cp(2)Ru(2)(mu-CH=CH2)(CO)(2)(SiR(3)) and vinylsilane: A model system for production of an olefinic product from a vinylidene intermediate