Metal-metal d-d interaction through the discrete stacking of mononuclear M(II) complexes (M = Pt, Pd, and Cu) within an organic-pillared coordination cage
英文:
Metal−Metal d−d Interaction through the Discrete Stacking of Mononuclear M(II) Complexes (M = Pt, Pd, and Cu) within an Organic-Pillared Coordination Cage
Two molecules of planar MII(acac)2 complexes (M = Pt, Pd, and, Cu; acac = acetylacetonato) are efficiently stacked within an organic-pillared coordination cage, exhibiting characteristic spectroscopies (for M = Pt and Pd) and electron spin−spin coupling (for M = Cu) attributable to metal−metal interaction.
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