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タイトル
和文:Rhodium-Catalyzed Enantioselective [2 + 2 + 1] Cycloaddition of 1,6-Enynes with Cyclopropylideneacetamides. 
英文:Rhodium-Catalyzed Enantioselective [2 + 2 + 1] Cycloaddition of 1,6-Enynes with Cyclopropylideneacetamides. 
著者
和文: Shunsuke Suzuki, Shuhei Nishigaki, Yu Shibata, Ken. Tanaka.  
英文: Shunsuke Suzuki, Shuhei Nishigaki, Yu Shibata, Ken. Tanaka.  
言語 English 
掲載誌/書名
和文:Organic Letters 
英文:Organic Letters 
巻, 号, ページ Vol. 20    No. 23    pp. 7461-7465
出版年月 2018年11月20日 
出版者
和文:American Chemical Society 
英文:American Chemical Society 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1021/acs.orglett.8b03235
アブストラクト It has been established that a cationic rhodium(I)/(R)-tol-BINAP or (R)-BINAP complex catalyzes the enantioselective [2 + 2 + 1] cycloaddn. of 1,6-enynes, possessing monosubstituted alkene units, with cyclopropylideneacetamides at room temp. through the elimination of ethylene to give bicyclic (cyclopent-2-en-1-ylidene)acetamides with high enantioselectivity. [on SciFinder(R)]

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