論文

• Akihiko Takahashi, Yuko Hirose, Hiroyuki Kusama, Nobuharu Iwasawa. Chelation-assisted Electrocyclic Reactions of 3-Alkenyl-2,2’-Bipyridines: An Efficient Method for the Synthesis of 5,6-Dihydro-1,10-phenanthrolines and 1,10-Phenanthrolines, Chem. Commun., p. 609-611, 2008.
• Hiroyuki Kusama, Kento Ishida, Hideaki Funami, Nobuharu Iwasawa. Platinum(II)-Catalyzed Reaction of γ,δ-Ynones with Alkenes for the Construction of 8-Oxabicyclo[3.2.1]octane Skeletons: Generation of Platinum-Containing Carbonyl Ylides from Acyclic Precursors,, Angew. Chem. Int. Ed., pp. accepted, 2008.
• Yuji Onizawa, Hiroyuki Kusama, Nobuharu Iwasawa. Efficient Control of π-Alkyne and Vinylidene Complex Pathways for the W(CO)5(L)-Catalyzed Synthesis of Two Types of Nitrogen-Containing Bicyclic Compounds, J. Am. Chem. Soc., Vol. 130, p. 802-803, 2008.
• Antoine Grandmarre, Hiroyuki Kusama, Nobuharu Iwasawa. W(CO)5(L)-Catalyzed Cyclization of ω−Acetylenic Silyl Enol Ethers for the Preparation of Nitrogen-Containing Cyclic Compounds, Chem. Lett., Vol. 36, p. 66-67, 2007.
• Hiroyuki Kusama, Hideaki Funami, Nobuharu Iwasawa. Synthesis of Naphthalene Derivatives through Platinum(II)-Catalyzed Reaction of 2-Alkynylbenzoates with Vinyl Ethers, Synthesis, p. 2014-2024, 2007.
• Tomoya Miura, Koichi Kiyota, Hiroyuki Kusama, Nobuharu Iwasawa. W(CO)5(L)-catalyzed 6-endo-selective cyclization and formal Cope rearrangement of allenyl silyl enol ethers, J. Organomet. Chem., Vol. 692, p. 562-568, 2007.
• Hideaki Funami, Hiroyuki Kusama, Nobuharu Iwasawa. Preparation of Substituted Cyclopentadienes through Platinum(II)-Catalyzed Cyclization of 1,2,4-Trienes: the Presence of Platinum-Carbene Complex Intermediate, Angew. Chem. Int. Ed., Vol. 46, pp. 909-911, 2007.
• H. Kusama, Y. Miyashita, J. Takaya, N. Iwasawa. Pt(II)- or Au(III)-Catalyzed [3+2] Cycloaddition of Metal-Containing Azomethine Ylides: Highly Efficient Synthesis of Mitosene Skeleton, Organic Letters, Vol. 8, pp. 289, 2006.
• H. Kusama, Y. Onizawa, N. Iwasawa. W(CO)5(L)-Catalyzed Tandem Intramolecular Cyclopropanation / Cope Rearrangement for the Stereoselective Construction of Bicyclo[5.3.0]decane Framework, J. Am. Chem. Soc., Vol. 128, pp. 16500, 2006.
• H. Kusama, T. Sawada, A. Okita, F. Shiozawa, N. Iwasawa. Synthesis of Isochromene Derivatives by 1,6-Addition of Nucleophiles to Benzopyranylidenetungsten Complex, Organic Letters, Vol. 8, pp. 1077, 2006.
• H. Kusama, Y. Suzuki, J. Takaya, N. Iwasawa. Intermolecular 1,5-Dipolar Cycloaddition Reaction of Tungsten-Containing Vinyl-Azomethine Ylides Leading to Seven-Membered Heterocycles, Organic Letters, Vol. 8, pp. 895, 2006.
• H. Kusama, H. Funami, M. Shido, Y. Hara, J. Takaya, N. Iwasawa. Generation and Reaction of Tungsten-Containing Carbonyl Ylides: [3+2]- Cycloaddition Reaction with Electron-Rich Alkenes, Journal of the American Chemical Society, Vol. 127, pp. 2709, 2005.
• H. Kusama, H. Yamabe, Y. Onizawa, T. Hoshino, N. Iwasawa. Rhenium(I)-Catalyzed Intramolecular Geminal Carbo-functionalization of Alkynes: Tandem Cyclization of ω-Acetylenic Dienol Silyl Ethers, Angewandte Chemie International Edition, Vol. 44, pp. 468, 2005.
• H. Yamabe, A. Mizuno, H. Kusama, N. Iwasawa. Rh(I)-Catalyzed Cyclization of 1-Arylprop-2-yn-1-ol Derivatives Utilizing Rhodium 1,4-Migration, Journal of the American Chemical Society, Vol. 127, pp. 3248, 2005.
• J. Takaya, H. Kusama, N. Iwasawa. Isolation and Reaction of (Indolin-3-ylidene)pentacarbonyltungsten Generated from Tungsten-Containing Azomethine Ylide, Chemistry Letters, Vol. 33, pp. 16-17, 2004.
• H. Kusama, H. Funami, J. Takaya, N. Iwasawa. Platinum(II)-Catalyzed Cycloaddition Reaction of 2-Alkynylbenzoates or Benzothioates with Vinyl Ethers: A Concise Method for Synthesis of 1-Acyl-4-alkoxy- or 1-Acyl-4-alkylsulfanyl-naphthalene Derivatives, Organic Letters, Vol. 6, pp. 605, 2004.
• N. Iwasawa, H. Kusama, K. Maeyama. W(CO)5(L)-Catalyzed Construction of Cyclic Carbon Frameworks, Journal of Synthetic Organic Chemistry, Japan, Vol. 60, No. 11, pp. 1036, 2002.
• H. Kusama, Y. Hokuto, N. Iwasawa. W(CO)5-Amine Catalyzed Exo- and Endo-Selective Cyclizations of w-Alkynyl Silyl Enol Ethers:A Highly Useful Method for the Construction of Polycyclic Compounds, Organic Letters, Vol. 4, pp. 2569, 2002.
• H. Kusama, J. Takaya, N. Iwasawa. A Facile Method for the Synthesis of Polycyclic Indole Derivatives: The Generation and Reaction of Tungsten-Containing Azomethine Ylides, Journal of the American Chemical Society, Vol. 124, pp. 11592, 2002.
• N. Iwasawa, M. Shido, H. Kusama. Generation and Reaction of Metal-Containing Carbonyl Ylides: Tandem [3+2]-Cycloaddition and Carbene Insertion Leading to Novel Polycyclic Compounds, Journal of the American Chemical Society, Vol. 123, pp. 5814, 2001.
• I. Kuwajima, H. Kusama. Enantioselective Total Synthesis of (+)-Taxusin and (-)-Taxol, Journal of Synthetic Organic Chemistry, Japan, Vol. 58, pp. 172, 2000.
• N. Iwasawa, M. Shido, H. Kusama. Novel Synthesis of Pentacarbonylbenzopyranylidenetungsten(0) Complexes and their Diels-Alder Reaction with Electron-Rich Alkenes, Journal of the American Chemical Society, Vol. 122, pp. 10226, 2000.
• H. Kusama, R. Hara, S. Kawahara, T. Nishimori, H. Kashima, N. Nakamura, K. Morihira, I. Kuwajima. Enantioselective Total Synthesis of (-)-Taxol, Journal of the American Chemical Society, Vol. 122, pp. 3811, 2000.
• R. Hara, T. Furukawa, H. Kashima, H. Kusama, Y. Horiguchi, I. Kuwajima. Enantioselective Total Synthesis of (+)-Taxusin, Journal of the American Chemical Society, Vol. 121, pp. 3072, 1999.
• K. Morihira, R. Hara, S. Kawahara, T. Nishimori, N. Nakamura, H. Kusama, I. Kuwajima. Enantioselective Total Synthesis of Taxol, Journal of the American Chemical Society, Vol. 120, pp. 12980-12981, 1998.
• H. Kusama, Y. Yamashita, K. Uchiyama, K. Narasaka. Transformation of Oximes of Phenethyl Ketone Derivatives to Quinolines and Azaspirotrienones Catalyzed by Tetrabutylammonium Perrhenate and Trifluoromethanesulfonic Acid., Bulletin of the Chemical Society of Japan, Vol. 70, pp. 965, 1997.

その他の論文・著書など

• H. Kusama, N. Iwasawa. Cycloaddition Reactions of Transition Metal-containing Benzopyrylium and Related Zwitterionic Intermediates, Chemistry Letters, Vol. 35, pp. 1082, 2006.

学位論文

• レニウム化合物を触媒とする有機合成反応の開発,  本文,  Doctor of Science,  東京大学,  1995/--/--, 

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