論文

• Takahiro Komaki, Yu Sato, Ken Tanaka, Yuki Nagashima. Visible-Light-Induced trans-Hydroboration of Diaryl Alkynes Utilizing Excited State of Borate Complexes, Org. Lett., Vol. 26, pp. 2180-2185, Mar. 2024.
• Shunsuke Emi, Shintaro Hamada, Yuko Kishida, Yu Sato, Futo Morita, Yuki Nagashima, hidehiro UEKUSA, Ken Tanaka. Rh-Catalyzed Enantioselective Hydroalkenylative Cyclization of 1,6-Enynes Constructing All-Carbon Quaternary Stereocenters, ACS Catal., Vol. 14, pp. 4951-4957, Mar. 2024.
• Li-Hsiang Wang, Juntaro Nogami, Yuki Nagashima, Ken Tanaka. Enantioselective Synthesis of Axially Chiral Figure-Eight Spirocycloparaphenylenes via Rh-Catalyzed Intermolecular [2 + 2 + 2] Cycloaddition, Organic Letters, Vol. 25, 4225-4230, June 2023.  公式リンク  
  
• Yuki Nagashima, Seiya Ouchi, Tomonori Inoue, Ken Tanaka. Computational Mechanistic Study on Intramolecular Triple Cyclization of 1-Biphenylethynyl-2-phenylethynylbenzenes Giving Spiro Fluorene-Phenylenevinylenes by Dual Catalysis, Bull. Chem. Soc. Jpn., Vol. 96, pp. 717-723, June 2023.
• Yu Sato, Masato Abekura, Tomohiro Oriki, Yuki Nagashima, Hidehiro Uekusa, Ken Tanaka. Shape‐ and Size‐Tunable Synthesis of Covalent Organic Cages through Rh‐Catalyzed Regioselective [2+2+2] Cycloaddition, Angewandte Chemie International Edition, Vol. 62, No. 24, e202304041, June 2023.  公式リンク  
  
• Juntaro Nogami, Daisuke Hashizume, Yuki Nagashima, Kazunori Miyamoto, Masanobu Uchiyama, Ken Tanaka. Catalytic stereoselective synthesis of doubly, triply and quadruply twisted aromatic belts, Nature Synthesis, Vol. 2, May 2023.  公式リンク  
  
• Eiki Tomita, Masahiro Kojima, Yuki Nagashima, Ken Tanaka, Haruki Sugiyama, Yasutomo Segawa, Atsushi Furukawa, Katsumi Maenaka, Satoshi Maeda, Tatsuhiko Yoshino, Shigeki Matsunaga. An Electron‐Deficient CpE Iridium(III) Catalyst: Synthesis, Characterization, and Application to Ether‐Directed C−H Amidation, Angewandte Chemie International Edition, Vol. 62, e202301259, May 2023.  公式リンク  
  
• Ryota Shimotsukue, Kohei Fujii, Yu Sato, Yuki Nagashima, Ken Tanaka. Rhodium‐Catalyzed Chemo‐, Regio‐, Diastereo‐, and Enantioselective Intermolecular [2+2+2] Cycloaddition of Three Unsymmetric 2π Components, Angewandte Chemie International Edition, Vol. 62, No. 16, e202304041, Apr. 2023.  公式リンク  
  
• Seiya Ouchi, Tomonori Inoue, Juntaro Nogami, Yuki Nagashima, Ken Tanaka. Design, synthesis and visible-light-induced non-radical reactions of dual-functional Rh catalysts, Nature Synthesis, Vol. 2, 535–547, Mar. 2023.  公式リンク  
  
• Yuya Kawai, Juntaro Nogami, Yuki Nagashima, Ken Tanaka. Stereoselective synthesis of [2.2]triphenylenophanes via intramolecular double [2 + 2 + 2] cycloadditions, Chemical Science, Vol. 14, 3963–3972., Mar. 2023.  公式リンク  
  
• Ryota Abe, Yuki Nagashima, Jin Tanaka, Ken Tanaka. Room Temperature Fluoranthene Synthesis through Cationic Rh(I)/H8-BINAP-Catalyzed [2 + 2 + 2] Cycloaddition: Unexpected Acceleration due to Noncovalent Interactions, ACS Catalysis, Vol. 13, 1604–1613, Feb. 2023.  公式リンク  
  
• Shiho Ishigaki, Yuki Nagashima, Daiki Yukimori, Jin Tanaka, Takashi Matsumoto, Kazunori Miyamoto, Masanobu Uchiyama, Ken Tanaka. Dearomative triple elementalization of quinolines driven by visible light, Nature Communications, Vol. 14, 652, Feb. 2023.  公式リンク  
  
• Takumi Wakikawa, Daichi Sekine, Yuta Murata, Youka Bunno, Masahiro Kojima, Yuki Nagashima, Ken Tanaka, Tatsuhiko Yoshino, Shigeki Matsunaga. Native Amide‐Directed C(sp 3 )−H Amidation Enabled by Electron‐Deficient Rh III Catalyst and Electron‐Deficient 2‐Pyridone Ligand, Angewandte Chemie International Edition, Vol. 61, e202213659, Dec. 2022.  公式リンク  
  
• Takumi Koshikawa, Juntaro Nogami, Yuki Nagashima, Ken Tanaka. Catalyst-Controlled Inter- and Intramolecular Cascade [4 + 2] Annulations via Benzopyrylium Intermediates, ACS Catalysis, Vol. 12, 14330–14336, Nov. 2022.  公式リンク  
  
• Ryo Arai, Yuki Nagashima, Takumi Koshikawa, Ken Tanaka. Photocatalytic Generations of Secondary and Tertiary Silyl Radicals from Silylboranes Using an Alkoxide Cocatalyst, The Journal of Organic Chemistry, Oct. 2022.  公式リンク  
  
• Futo Morita, Juntaro Nogami, Antônio Junio Araujo Dias, Suzuka Kinoshita, Yuki Nagashima, Ken Tanaka. Regiodivergent Synthesis and π‐Stacking‐Induced Chiral Self‐Recognition of Hexabenzocoronene‐Based [6]Helicenes, European Journal of Organic Chemistry, Vol. 2022, No. 27, e202200690, July 2022.  公式リンク  
  
• Daisuke Yokose, Yuki Nagashima, Suzuka Kinoshita, Juntaro Nogami, Ken Tanaka. Enantioselective Synthesis of Axially Chiral Styrene‐Carboxylic Esters by Rhodium‐Catalyzed Chelation‐Controlled [2+2+2] Cycloaddition, Angewandte Chemie International Edition, 61, 23, e202202542, Mar. 2022.
• Kohei Fujii, Yuki Nagashima, Takumi Shimokawa, Junichiro Kanazawa, Haruki Sugiyama, Koji Masutomi, Hidehiro Uekusa, Masanobu Uchiyama, Ken Tanaka. Stereoselective cyclohexadienylamine synthesis through rhodium-catalysed [2+2+2] cyclotrimerization, Nature Synthesis, 1, 365-375, Mar. 2022.
• Li-Hsiang Wang, Yuki Nagashima, Masato Abekura, Hidehiro Uekusa, Gen-ichi Konishi, Ken Tanaka. Rhodium‐Catalyzed Intermolecular Cycloaromatization Route to Cycloparaphenylenes that Exhibit Aggregation‐Induced Emission, Chemistry – A European Journal, 28, 21, e202200064, Feb. 2022.
• Juntaro Nogami, Yuki Nagashima, Kazunori Miyamoto, Haruki Sugiyama, Yusuke Tanaka, Hidehiro Uekusa, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka. Synthesis of Cyclophenacene‐ and Chiral‐Type Cyclophenylene–Naphthylene Belts, Angewandte Chemie International Edition, 61, 15, e202200800, Feb. 2022.
• Antônio Junio Araujo Dias, Hiroto Takahashi, Juntaro Nogami, Yuki Nagashima, Ken Tanaka. Oxidative [4 + 2] annulation of 1-naphthols with alkynes accelerated by an electron-deficient rhodium(iii) catalysts, Organic & Biomolecular Chemistry, 20, 5, 1008-1012, Dec. 2021.
• Yuki Nagashima, Shiho Ishigaki, Jin Tanaka, Ken Tanaka. Acceleration Mechanisms of C–H Bond Functionalization Catalyzed by Electron-Deficient CpRh(III) Complexes, ACS Catalysis, 11, 21, 13591-13602, Oct. 2021.
• Jin Tanaka, Yuki Nagashima, Antônio Junio Araujo Dias, Ken Tanaka. Photo-Induced ortho-C–H Borylation of Arenes through In Situ Generation of Rhodium(II) Ate Complexes, Journal of the American Chemical Society, 143, 30, 11325-11331, Aug. 2021.
• Kyoka Sakamoto, Yuki Nagashima, Chao Wang, Kazunori Miyamoto, Ken Tanaka, Masanobu Uchiyama. Illuminating Stannylation, Journal of the American Chemical Society, Apr. 2021.  公式リンク  
  
• Juntaro Nogami, Yuki Nagashima, Kazunori Miyamoto, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka. Asymmetric synthesis, structures, and chiroptical properties of helical cycloparaphenylenes, Chemical Science, 12, 22, 7858-7865, Apr. 2021.
• Kyoichi Hanada, Juntaro Nogami, Kazunori Miyamoto, Norihiko Hayase, Yuki Nagashima, Yusuke Tanaka, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka. Rhodium‐Catalyzed Enantioselective Synthesis, Structures, and Properties of Single and Double Azahelicene‐Like Molecules, Chemistry – A European Journal, 27, 9313-9319, Apr. 2021.
• Seiya Ouchi, Takumi Koshikawa, Yuki Nagashima, Ken Tanaka. Platinum-Catalyzed Intramolecular Spirocyclization of N-(Methylnaphthalenyl)propiolamides via Formal Aromatic Ene Reaction, Organic Letters, Mar. 2021.  公式リンク  
  
• Hiroto Takahashi, Yuki Nagashima, Ken Tanaka. Rhodium(III)‐Catalyzed Oxidative Intramolecular 1,1‐Oxyamination of Alkenes with Protected Amino Acids to Produce Oxazoloisoindole‐2,5‐diones, Mar. 2021.  公式リンク  
  
• Takumi Koshikawa, Yuki Nagashima, Ken Tanaka. Gold-Catalyzed [3 + 2] Annulation, Carbenoid Transfer, and C–H Insertion Cascade: Elucidation of Annulation Mechanisms via Benzopyrylium Intermediates, ACS Catalysis, pp. 1932-1937, Feb. 2021.  公式リンク  
  
• Hiroto Takahashi, Yusaku Honjo, Yu Shibata, Yuki Nagashima, Ken Tanaka. Dienylation of Unfunctionalized Arenes with 1,6-Diynes via Rhodium-Catalyzed Directing-Group-Free C–H Bond Activation, Synthesis, Dec. 2020.
• Ken Tanaka, Yuki Nagashima, Jin Tanaka. Rhodium(III)-Catalyzed Oxidative Ortho-Olefination of Phenyl Carbamates with Alkenes: Elucidation of Acceleration Mechanisms by an Unsubstituted Cyclopentadienyl Ligand, Org. Lett., 22, 7181–7186, Nov. 2020.
• Masaki Kondo, Junichiro Kanazawa, Tomohiro Ichikawa, Takumi Shimokawa, Yuki Nagashima, Kazunori Miyamoto, Masanobu Uchiyama. Silaboration of [1.1.1]Propellane: A Storable Feedstock for Bicyclo[1.1.1]pentane Derivatives, Angewandte Chemie International Edition, Jan. 2020.  公式リンク  
  
• Daiki Yukimori, Yuki Nagashima, Chao Wang, Atsuya Muranaka, Masanobu Uchiyama. Quadruple Borylation of Terminal Alkynes, Journal of the American Chemical Society, June 2019.  公式リンク  
  
• Kumiko Kojima, Yuki Nagashima, Chao Wang, Masanobu Uchiyama. In Situ Generation of Silyl Anion Species through Si−B Bond Activation for the Concerted Nucleophilic Aromatic Substitution of Fluoroarenes, ChemPlusChem, Vol. 84, No. 3, pp. 277-280, Mar. 2019.  公式リンク  
  
• Nagashima, Y., Yukimori, D., Wang, C., Uchiyama, M., Yuki Nagashima, Daiki Yukimori, Chao Wang, Masanobu Uchiyama. In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes, Angewandte Chemie - International Edition, Vol. 57, No. 27, pp. 8053-8057, July 2018.
• Yuki Nagashima, Keiichi Hirano, Ryo Takita, Masanobu Uchiyama. Trans-diborylation of alkynes: pseudo-intramolecular strategy utilizing a propargylic alcohol unit., Journal of the American Chemical Society, June 2014.
• Yuki Nagashima, Ryo Takita, Kengo Yoshida, Keiichi Hirano, Masanobu Uchiyama. Design, generation, and synthetic application of borylzincate: borylation of aryl halides and borylzincation of benzynes/terminal alkyne., Journal of the American Chemical Society, Dec. 2013.  公式リンク  
  

著書

• 永島佑貴. 反応中間体の光励起を活用する新たな光反応, 月刊「化学と工業」, Vol. 10, Oct. 2022.
• 永島佑貴. 光を利用する典型元素化合物の新合成法と低分子医薬品の多様化, 月刊「アグリバイオ」, Vol. 6, No. 10, 61-65, Aug. 2022.
• 永島佑貴. 光が拓く典型元素化合物の新合成法と低分子モダリティの多様化, 月刊「細胞」, Vol. 8, 28–31, July 2022.
• 永島 佑貴, 田中 健, 内山 真伸. 約50年ぶりに誕生したスズ化学種の新しい仲間 ―励起状態を利用してつくりだした反応活性種―, 月刊「化学」10月号, Sept. 2021.

国際会議発表 (査読なし・不明)

• Yuki Nagashima. Direct Excitation Strategy of Intermediates Enabling Photo-induced Borylation and Stannylation, The 25th IUPAC International Conference on Physical Organic Chemistry 25 (ICPOC25), July 2022.

国内会議発表 (査読なし・不明)

• 永島佑貴. 理論計算と光エネルギーで切り拓く多様な分子変換反応の開発, 第29回 RISMセミナー on 有機化学とソフトマテリアル, Dec. 2022.
• 永島佑貴. ヘテロ元素と理論計算で切り拓く光反応, 京都大学第7回有機若手ワークショップ, Nov. 2022.
• Yuki Nagashima. Designed reactive complexes enabling photo-induced elementalization reactions, 錯体化学会 第72回討論会, Sept. 2022.
• 永島佑貴. 反応活性種の直接光励起を利用するホウ素化・スズ化反応, 2022年度 有機合成化学協会 若手研究者のためのセミナー, July 2022.
• 永島佑貴. 反応活性種の光励起状態を利用するヘテロ元素導入反応の開発, 日本化学会第102春季年会, Mar. 2022.
• 永島 佑貴, 坂本 京花, 田中 健, 内山 真伸. スズアニオンの励起状態を利用した新規スタニル化反応, 第48回有機典型元素化学討論会, Dec. 2021.
• 永島 佑貴, 田中仁, Antonio Junio Araujo Dias, 田中 健. 光励起状態を利用した Cp ロジウム(III)触媒による芳香環のC–Hホウ素化反応, 第67回有機金属化学討論会, Sept. 2021.

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